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(Z)-3-(2-{2-[1-(4-羟基苯基)亚乙基]肼基-1-基}-1,3-噻唑-4-基)-2H-色原酮-2-酮

(Z)-3-(2-{2-[1-(4-Hy-droxy-phen-yl)ethyl-idene]hydrazin-1-yl}-1,3-thia-zol-4-yl)-2H-chromen-2-one.

作者信息

Arshad Afsheen, Osman Hasnah, Lam Chan Kit, Quah Ching Kheng, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):o1632-3. doi: 10.1107/S1600536810021604.

Abstract

In the title compound, C(20)H(15)N(3)O(3)S, an intra-molecular C-H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thia-zole and benzene rings. The thia-zole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O-H⋯O hydrogen bonds link the mol-ecules into a zigzag chain along [20]. Weak N-H⋯O and C-H⋯O inter-actions connect the chains into a three-dimensional network. π-π stacking inter-actions with a centroid-centroid distance of 3.4209 (14) Å are also observed between the chains.

摘要

在标题化合物C₂₀H₁₅N₃O₃S中,分子内的C—H⋯O氢键形成了一个S(6)环模式。色烯环系统相对于噻唑环和苯环的二面角分别为14.21 (9)°和9.91 (10)°。噻唑环与苯环的二面角为24.06 (11)°。在晶体结构中,O—H⋯O氢键将分子沿[20]连接成锯齿链。弱的N—H⋯O和C—H⋯O相互作用将这些链连接成三维网络。链之间还观察到质心间距为3.4209 (14) Å的π-π堆积相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6181/3006946/09279178f70d/e-66-o1632-fig1.jpg

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