Al-Dajani Mohammad T M, Abdallah Hassan H, Mohamed Nornisah, Goh Jia Hao, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1815-6. doi: 10.1107/S160053681002427X.
In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(-)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter-molecular O-H⋯Cl hydrogen bonds link the water mol-ecules and chloride anions into an R(4) (4)(8) ring motif. Inter-molecular N-H⋯Cl, C-H⋯Cl and C-H⋯O hydrogen bonds further inter-connect these rings with the organic cations into a two-dimensional network parallel to the bc plane.
在标题化合物C(13)H(20)N(3) (+)·Cl(-)·H(2)O的有机阳离子中,两个吡咯烷环呈扭曲构象。吡啶环与吡咯烷环的平均平面形成的二面角分别为14.57 (6)°和23.96 (6)°。在晶体结构中,成对的分叉分子间O-H⋯Cl氢键将水分子和氯离子连接成R(4) (4)(8)环 motif。分子间的N-H⋯Cl、C-H⋯Cl和C-H⋯O氢键进一步将这些环与有机阳离子相互连接,形成一个平行于bc平面的二维网络。