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一种使用功能化卟啉在 ITO/液体界面进行光诱导电子输运动态研究的新方法。

A novel method for dynamic investigations of photoinduced electron transport using functionalized-porphyrin at ITO/liquid interface.

机构信息

Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou, 730070, China.

出版信息

Chem Commun (Camb). 2011 Jun 28;47(24):6975-7. doi: 10.1039/c1cc10842e. Epub 2011 May 23.

DOI:10.1039/c1cc10842e
PMID:21603711
Abstract

A new scanning electrochemical microscopy (SECM) model provided a two-dimensional quantitative analysis on a heterogeneous electron transport (ET) process of a functionalized porpyrin by photoinduced ET at the ITO/liquid interface. The basic features of oxidized porphyrin under light source were recorded by feedback approach curves within the framework of the bimolecular ET mechanisms.

摘要

一种新的扫描电化学显微镜（SECM）模型通过在 ITO/液体界面处的光诱导电子转移（ET），对功能化卟啉的非均相电子传递（ET）过程提供了二维定量分析。在双分子 ET 机制的框架内，通过反馈方法曲线记录了光源下氧化卟啉的基本特征。

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