通过封装 Keggin 多金属氧酸盐来提高 Cu3(BTC)2 金属有机骨架在蒸汽条件下的稳定性。
Stability improvement of Cu3(BTC)2 metal-organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate.
机构信息
Center for Surface Chemistry and Catalysis, Department of Microbial and Molecular Systems, KU Leuven, Belgium 3000.
出版信息
Chem Commun (Camb). 2011 Jul 28;47(28):8037-9. doi: 10.1039/c1cc12341f. Epub 2011 Jun 15.
PMID:21674103
Abstract
Cu(3)(BTC)(2) with an incorporated Keggin polyoxometalate was demonstrated to be stable under steaming conditions up to 483 K, while the isostructural HKUST-1 degrades and transforms into Cu(2)OH(BTC)(H(2)O)·2nH(2)O from 343 K onwards.
摘要
在 483 K 的蒸汽条件下，负载多金属氧酸盐的 Cu(3)(BTC)(2) 表现出很好的稳定性，而结构相同的 HKUST-1 则从 343 K 开始降解，并转化为 Cu(2)OH(BTC)(H(2)O)·2nH(2)O。
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