Department of Chemistry, University of York, Heslington, York, UK YO10 5DD.
Org Biomol Chem. 2011 Aug 7;9(15):5573-8. doi: 10.1039/c1ob05475a. Epub 2011 Jun 27.
Disproportionation of TEMPO in acids leads to the formation of an N-oxoammonium salt, which can further decompose under thermal conditions, yielding the corresponding hydroxylamine, N(2)O, CO(2) and a series of dimerisation products. Overall, acid-catalysed thermal decay of TEMPO leads to ca. 80% yield of hydroxylamine.
TEMPO 在酸中的歧化导致形成 N-氧代铵盐，该盐在热条件下进一步分解，生成相应的羟胺、N(2)O、CO(2)和一系列二聚产物。总体而言，TEMPO 在酸催化下的热降解导致羟胺的收率约为 80%。
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