Department of Materials Science and Engineering, University of Florida, PO Box 116400, Gainesville, Florida 32611-6400, United States.
ACS Appl Mater Interfaces. 2011 Jul;3(7):2200-3. doi: 10.1021/am200527j. Epub 2011 Jul 5.
Carbon-based nanomaterials such as carbon nanotubes and graphene are excellent candidates for superhydrophobic surfaces because of their intrinsically high surface area and nonpolar carbon structure. This paper demonstrates that graphene aerogels with a silane surface modification can provide superhydrophobicity. Graphene aerogels of various concentrations were synthesized and the receding contact angle of a water droplet was measured. It is shown that graphene aerogels are hydrophobic and become superhydrophobic following the application of a fluorinated surfactant. The aerogels produced for this experiment outperform previous carbon nanomaterials in creating superhydrophobic surfaces and offer a more scalable synthetic procedure for production.
碳基纳米材料,如碳纳米管和石墨烯,因其具有高比表面积和非极性碳结构,是超疏水表面的理想选择。本文证明了经过硅烷表面修饰的石墨烯气凝胶可以提供超疏水性。合成了不同浓度的石墨烯气凝胶,并测量了水滴的后退接触角。结果表明,石墨烯气凝胶具有疏水性,经过氟化物表面活性剂的应用后变为超疏水性。与之前的碳纳米材料相比,本实验制备的气凝胶在超疏水表面的制备方面表现更优,并且提供了更具可扩展性的合成方法。