Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan.
Science. 2011 Jul 1;333(6038):68-71. doi: 10.1126/science.1202232.
In superelastic alloys, large deformation can revert to a memorized shape after removing the stress. However, the stress increases with increasing temperature, which limits the practical use over a wide temperature range. Polycrystalline Fe-Mn-Al-Ni shape memory alloys show a small temperature dependence of the superelastic stress because of a small transformation entropy change brought about by a magnetic contribution to the Gibbs energies. For one alloy composition, the superelastic stress varies by 0.53 megapascal/°C over a temperature range from -196 to 240°C.
在超弹性合金中,在去除应力后,大变形可以恢复到记忆形状。然而,随着温度的升高,应力会增加,这限制了其在较宽温度范围内的实际应用。多晶 Fe-Mn-Al-Ni 形状记忆合金由于磁对吉布斯能的贡献导致相变熵变较小,因此其超弹性应力的温度依赖性较小。对于一种合金成分,在-196 至 240°C 的温度范围内,超弹性应力变化 0.53 兆帕斯卡/°C。