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Bis(2,4-dichloro-phen-oxy-acetato-κO,O)(5,5'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II).

作者信息

Ji Li-Li, Liu Jian-She, Song Wen-Dong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m493. doi: 10.1107/S1600536811010579. Epub 2011 Mar 26.

Abstract

In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro-phen-oxy-acetate ligands and two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, displaying a distorted octa-hedral geometry. A three-dimensional supra-molecular structure is formed through inter-molecular C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine and benzene rings [centroid-centroid distance = 3.779 (2) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/91d3/3099758/07b7e660356a/e-67-0m493-fig1.jpg

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