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1,3-二苄基-1H-蒽并[1,2-d]咪唑-2,6,11(3H)-三酮

1,3-Dibenzyl-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione.

作者信息

Afrakssou Zahra, Kandri Rodi Youssef, Capet Frédéric, Essassi El Mokhtar, El Ammari Lahcen

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1253-4. doi: 10.1107/S1600536811015078. Epub 2011 Apr 29.

Abstract

The mol-ecule of the title compound, C(29)H(20)N(2)O(3), contains four fused rings, three are six-membered rings and one is the five-membered imidazole ring. The fused-ring system is linked to two benzyl groups. The four fused rings are folded around the O=C⋯C=O direction of the anthraquinone, with a dihedral angle of 16.36 (8)° between the two terminal rings (A and D). The imidazole ring (D) is almost perpendicular to the two benzyl groups (E and F) with dihedral angles of 86.69 (17) and 83.15 (13)°, respectively. In the crystal, adjacent mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonding.

摘要

标题化合物C(29)H(20)N(2)O(3)的分子包含四个稠环,其中三个是六元环,一个是五元咪唑环。稠环体系与两个苄基相连。四个稠环围绕蒽醌的O=C⋯C=O方向折叠,两个末端环(A和D)之间的二面角为16.36 (8)°。咪唑环(D)几乎垂直于两个苄基(E和F),二面角分别为86.69 (17)°和83.15 (13)°。在晶体中,相邻分子通过分子间C-H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fca4/3089129/68818584db7e/e-67-o1253-fig1.jpg

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