光化学控制富电子炔烃与四氰乙烯的高效加成反应。
Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene.
机构信息
Department of Chemistry, Rikkyo University, Toshima-ku, Tokyo, Japan.
出版信息
Chem Commun (Camb). 2011 Sep 21;47(35):9819-21. doi: 10.1039/c1cc13476k. Epub 2011 Jul 28.
PMID:21799962
Abstract
The electron density of an alkyne moiety is enhanced by the photochromic ring closure of a diarylethene derivative, which allows the thermal addition reaction with a small π-acceptor, tetracyanoethylene, at room temperature.
摘要
炔烃部分的电子密度由于二芳基乙烯衍生物的光致变色环闭合而增强，这使得其能够在室温下与小的π-受体四氰乙烯进行热加成反应。
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