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KBr/InSb体系上的PTCDA分子:低温扫描隧道显微镜研究

PTCDA molecules on a KBr/InSb system: a low temperature STM study.

作者信息

Such B, Goryl G, Godlewski S, Kolodziej J J, Szymonski M

机构信息

Centre for Nanometer-Scale Science and Advanced Materials (NANOSAM), Faculty of Physics, Astronomy, and Applied Computer Science, Jagiellonian University, Reymonta 4, 30-059 Krakow, Poland.

出版信息

Nanotechnology. 2008 Nov 26;19(47):475705. doi: 10.1088/0957-4484/19/47/475705. Epub 2008 Oct 30.

Abstract

We have used scanning tunnelling microscopy (STM) at 77 K to investigate 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) molecules adsorbed on an ultrathin (1-2 monolayer (ML)) film of KBr grown on a c(8 × 2)InSb(001) substrate. The molecules are stabilized both at the KBr steps and on the terraces. On the 1 ML film the PTCDA molecules appear predominantly as single entities, whereas on the 2 ML film formation of molecular clusters is preferred. Differences in the adsorption configurations indicate that the interaction between the molecules and the surface differs significantly for the cases of 1 and 2 ML films. We present images of the molecules obtained with sub-molecular resolution for both filled and empty state sampling modes. We argue that the highest occupied molecular orbital (the lowest unoccupied molecular orbital) is responsible for intramolecular contrast in filled (empty) state images of the molecules, even though they are deformed due to strong interaction with the substrate.

摘要

我们利用77K温度下的扫描隧道显微镜(STM)研究了吸附在生长于c(8×2)InSb(001)衬底上的超薄(1 - 2单层(ML))KBr薄膜上的3,4,9,10 - 苝四羧酸二酐(PTCDA)分子。这些分子在KBr台阶处和台面上均能稳定存在。在1 ML薄膜上,PTCDA分子主要以单个实体形式出现,而在2 ML薄膜上则更倾向于形成分子簇。吸附构型的差异表明,对于1 ML和2 ML薄膜的情况,分子与表面之间的相互作用存在显著差异。我们展示了在填充态和空态采样模式下以亚分子分辨率获得的分子图像。我们认为,尽管分子由于与衬底的强相互作用而发生变形,但最高占据分子轨道(最低未占据分子轨道)是分子填充态(空态)图像中分子内对比度的原因。

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