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通过 {331} 高指数晶面连接的具有凹三角二十面体结构的 Pd@Au 核壳纳米晶体的简便合成及其电化学发光应用。

Facile synthesis and electrochemiluminescence application of concave trisoctahedral Pd@Au core-shell nanocrystals bound by {331} high-index facets.

机构信息

State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

出版信息

Chem Commun (Camb). 2011 Oct 7;47(37):10353-5. doi: 10.1039/c1cc13344f. Epub 2011 Aug 17.

Abstract

Concave trisoctahedral (TOH) Pd@Au core-shell nanocrystals bound by {331} facets have been synthesized for the first time. Pd nanocubes and cetyltrimethylammonium chloride were used as the structure-directing cores and capping agents, respectively. Their optical and electrocatalytic properties were investigated.

摘要

首次合成了具有{331}面的凹八面体(TOH)Pd@Au 核壳纳米晶体。Pd 纳米立方体和十六烷基三甲基氯化铵分别用作结构导向核和封端剂。研究了它们的光学和电化学催化性能。

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