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模拟油炸对橄榄油渣提取物富化后的植物油抗氧化剂成分的影响。

Influence of simulated deep frying on the antioxidant fraction of vegetable oils after enrichment with extracts from olive oil pomace.

机构信息

Department of Analytical Chemistry, Annex Marie Curie Building, Campus of Rabanales, Institute of Biomedical Research Maimónides (IMIBIC), Reina Sofía Hospital, and Andalusian Institute of Fine Chemistry and Nanotechnology (IAQFN), University of Córdoba, E-14071 Córdoba, Spain.

出版信息

J Agric Food Chem. 2011 Sep 28;59(18):9806-14. doi: 10.1021/jf2019159. Epub 2011 Sep 1.

Abstract

The stability of the antioxidant fraction in edible vegetable oils has been evaluated during a simulated deep frying process at 180 °C. Four edible oils (i.e., extra-virgin olive oil with a 400 μg/mL overall content in naturally existing phenols; high-oleic sunflower oil without natural content of these compounds but enriched either with hydrophilic antioxidants isolated from olive pomace or with an oxidation inhibitor, dimethylsiloxane; and sunflower oil without enrichment) were subjected to deep heating consisting of 20 cycles at 180 °C for 5 min each. An oil aliquot was sampled after each heating cycle to study the influence of heating on the antioxidant fraction composed of hydrophilic and lipophilic antioxidants such as phenols and tocopherols, respectively. The decomposition curves for each group of compounds caused by the influence of deep heating were studied to compare their resistance to oxidation. Thus, the suitability of olive pomace as raw material to obtain these compounds offers an excellent alternative to the use of olive-tree materials different from leaves. The enrichment of refined edible oils with natural antioxidants from olive pomace is a sustainable strategy to take benefits from this residue.

摘要

在 180°C 的模拟深度油炸过程中评估了食用植物油中抗氧化剂部分的稳定性。研究了四种食用油(即总酚含量为 400μg/mL 的特级初榨橄榄油;不含这些化合物的高油酸葵花籽油,但用橄榄渣中分离的亲水性抗氧化剂或氧化抑制剂二甲基硅氧烷进行了富化;以及未经富化的葵花籽油),在 180°C 下进行了 20 次加热循环,每次加热 5 分钟。在每次加热循环后抽取油样,以研究加热对由亲水性和疏水性抗氧化剂(如酚类和生育酚)组成的抗氧化剂部分的影响。研究了受深度加热影响的各化合物组的分解曲线,以比较它们的抗氧化能力。因此,橄榄渣作为获得这些化合物的原料的适宜性为使用不同于叶子的橄榄树材料提供了极好的替代方法。用橄榄渣中的天然抗氧化剂对精炼食用植物油进行富化是一种从这种残留物中获益的可持续策略。

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