Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
Phys Chem Chem Phys. 2011 Oct 14;13(38):17019-22. doi: 10.1039/c1cp22364j. Epub 2011 Sep 7.
Multiple charge-separation sites have successfully been constructed using supramolecular complexes of multiporphyrinic oligopeptides [P(ZnP)(n), n = 2, 4, 8] with fulleropyrrolidine bearing a pyridine or imidazole coordinating ligand, which are organized by utilizing π-π interaction in addition to the coordination bond.
利用具有吡啶或咪唑配位基团的富勒吡咯啉的多卟啉寡肽 [P(ZnP)(n),n = 2,4,8] 的超分子配合物,成功构建了多个电荷分离位点,这些配合物通过π-π 相互作用以及配位键进行组织。