Institut de Physique de la Matire Condense, Ecole Polytechnique Fédérale de Lausanne, Station 3, CH-1015 Lausanne, Switzerland.
J Magn Reson. 2011 Oct;212(2):440-9. doi: 10.1016/j.jmr.2011.08.022. Epub 2011 Aug 24.
A saddle coil manufactured by electric discharge machining (EDM) from a solid piece of copper has recently been realized at EPFL for Dynamic Nuclear Polarization enhanced Nuclear Magnetic Resonance experiments (DNP-NMR) at 9.4 T. The corresponding electromagnetic behavior of radio-frequency (400 MHz) and THz (263 GHz) waves were studied by numerical simulation in various measurement configurations. Moreover, we present an experimental method by which the results of the THz-wave numerical modeling are validated. On the basis of the good agreement between numerical and experimental results, we conducted by numerical simulation a systematic analysis on the influence of the coil geometry and of the sample properties on the THz-wave field, which is crucial in view of the optimization of DNP-NMR in solids.
最近,EPFL 利用电火花加工(EDM)从一块实心铜块中制造出了一种鞍形线圈,用于在 9.4T 下进行动态核极化增强核磁共振实验(DNP-NMR)。通过数值模拟研究了各种测量配置下射频(400MHz)和太赫兹(263GHz)波的相应电磁行为。此外,我们还提出了一种验证太赫兹波数值建模结果的实验方法。基于数值和实验结果之间的良好一致性,我们通过数值模拟对线圈几何形状和样品性质对太赫兹波场的影响进行了系统分析,这对于优化固态 DNP-NMR 至关重要。