Ostapenko T, Zhang C, Sprunt S N, Jákli A, Gleeson J T
Department of Physics, Kent State University, Kent, Ohio 44242, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Aug;84(2 Pt 1):021705. doi: 10.1103/PhysRevE.84.021705. Epub 2011 Aug 5.
The existence of the elusive biaxial phase has been the subject of much discussion since it was predicted by Freiser in 1970. More recently, there have been numerous attempts to find a thermotropic liquid crystal that exhibits a biaxial phase and with this, conflicting reports about whether such a phase has been positively identified in bent-core liquid crystals. One reason for the discrepancy is that there is currently no way to rule out surface effects or anchoring transitions, both of which may give a false positive identification of a uniaxial-biaxial nematic transition. We have developed a technique that uses a magnetic field to align the uniaxial director, thus widening its application to any bent-core nematic material.
自1970年弗雷泽预言难以捉摸的双轴相的存在以来,它一直是诸多讨论的主题。最近,人们进行了大量尝试,试图找到一种呈现双轴相的热致液晶,与此同时,关于在弯曲核液晶中是否已确切鉴定出这样一个相,出现了相互矛盾的报道。存在差异的一个原因是,目前没有办法排除表面效应或锚定转变,这两者都可能导致对单轴 - 双轴向列相转变的误判。我们开发了一种技术,利用磁场来排列单轴指向矢,从而将其应用范围扩展到任何弯曲核向列相材料。