卷柏素M，一种从垫状卷柏中提取的新型卷柏素衍生物。

Selaginellin M, a new selaginellin derivative from Selaginella pulvinata.

作者信息

Xu Kang-Ping, Zou Hui, Liu Guo-Ru, Long Hong-Ping, Li Jing, Li Fu-Shuang, Zou Zhen-Xin, Kuang Jun-Wei, Xie Xin, Tan Gui-Shan

机构信息

School of Pharmaceutical Sciences, Central South University, Changsha, 410013, China.

出版信息

J Asian Nat Prod Res. 2011 Oct;13(11):1051-5. doi: 10.1080/10286020.2011.617304. Epub 2011 Oct 10.

DOI:10.1080/10286020.2011.617304

PMID:21985670

Abstract

A new selaginellin derivative, selaginellin M (1), together with one known compound, selaginellin E (2), was isolated from Selaginella pulvinata. The structure of the new compound was elucidated and named as (R,S)-4-((4'-hydroxy-4-((2-hydroxyethoxy)methyl))-3-((4-hydroxyphenyl)ethynyl)biphenyl-2-yl)(4-hydroxyphenyl)methylene)cyclohexa-2,5-dienone on the basis of the spectroscopic data including UV, IR, 1D, and 2D NMR as well as HR-ESI-MS analysis.

摘要

从垫状卷柏中分离得到一种新的卷柏素衍生物——卷柏素M（1）以及一种已知化合物——卷柏素E（2）。基于紫外光谱（UV）、红外光谱（IR）、一维核磁共振（1D NMR）、二维核磁共振（2D NMR）以及高分辨电喷雾电离质谱（HR-ESI-MS）分析等光谱数据，阐明了该新化合物的结构，并将其命名为（R,S）-4-（（4'-羟基-4-（（2-羟基乙氧基）甲基））-3-（（4-羟基苯基）乙炔基）联苯-2-基）（4-羟基苯基）亚甲基）环己-2,5-二烯酮。