Electrochemical Power Systems Division, Central Electrochemical Research Institute, Karaikudi, Tamilnadu, India.
Chem Asian J. 2012 Jan 2;7(1):163-8. doi: 10.1002/asia.201100485. Epub 2011 Oct 14.
Pristine and Co-doped LiMnPO(4) have been synthesized by the sol-gel method using glycine as a chelating agent and the carbon composites were obtained by the wet ball mill method. The advantage of this method is that it does not require an inert atmosphere (economically viable) and facilitates a shorter time for synthesis. The LiCo(0.09)Mn(0.91)PO(4)/C nanocomposites exhibit the highest coulombic efficiency of 99 %, delivering a capacity of approximately 160 mAhg(-1) and retain a capacity of 96.3 % over the investigated 50 cycles when cycled between 3-4.9 V at a charge/discharge rate of 0.1 C.
采用甘氨酸作为螯合剂的溶胶-凝胶法合成了纯净和共掺杂的 LiMnPO4,并通过湿球磨法获得了碳复合材料。该方法的优点是不需要惰性气氛(经济可行),并且有利于缩短合成时间。LiCo(0.09)Mn(0.91)PO(4)/C 纳米复合材料表现出最高的库仑效率为 99%,在 3-4.9 V 的电压范围内以 0.1 C 的充放电速率循环 50 次后,其容量约为 160 mAhg(-1),容量保持率为 96.3%。