Wu Ying-Juan, Chen Yong-Heng, Yang Chun-Xia, Chang Xiang-Yang, Wang Chun-Lin, Liang Chun-Ying
School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2011 Sep;31(9):2561-4.
In the present paper, the correlations between sixteen elements from the dry method roasted dust-slag of pyrite and sixteen elements from the soil layer near and far from the store area were studied by ICP-MS. Similar radio and outstanding different radio of the elements between the dust-slag and the soil were studied too. It was discovered that in the pollution soil layer Tl, Cd, Cs, Cu, Zn, Mn, Pb and Ni were easy to be identified and had similar radio with the elements in the dust-slag. But only Tl, Cd, Zn and Ni are suitable for criterion of element similar properties. In dust-slag and soil, distinct composition element radios of Tl, Cs, Co, Mo, Zn, Cr, V, Sr, Sb, Pb, Rb, Mn and Ni had striking differentiation. Only Tl, V, Sb and Cu corresponded to both the uncorrelated elements analysis of surface layer and middle-base layer soil. Tl could be used as an inspection target of similar elements and outstanding different elements between the dust-slag and the soil in the meanwhile. So we suggested that Tl can be used as a symbolic element in the roasting dust-slag of pyrite to find the dust-slag of pyrite in dust-recognition and to differentiate the metallurgy dust of pyrite and soil dust.
本文采用电感耦合等离子体质谱法(ICP-MS)研究了硫铁矿干法焙烧烟尘渣中16种元素与储存区附近和远处土壤层中16种元素之间的相关性。同时也研究了烟尘渣与土壤中元素的相似放射性和显著不同放射性。研究发现,在污染土壤层中,铊(Tl)、镉(Cd)、铯(Cs)、铜(Cu)、锌(Zn)、锰(Mn)、铅(Pb)和镍(Ni)易于识别,且与烟尘渣中的元素具有相似放射性。但只有铊(Tl)、镉(Cd)、锌(Zn)和镍(Ni)适用于元素相似性标准。在烟尘渣和土壤中,铊(Tl)、铯(Cs)、钴(Co)、钼(Mo)、锌(Zn)、铬(Cr)、钒(V)、锶(Sr)、锑(Sb)、铅(Pb)、铷(Rb)、锰(Mn)和镍(Ni)的组成元素放射性存在显著差异。只有铊(Tl)、钒(V)、锑(Sb)和铜(Cu)与表层和中基层土壤的不相关元素分析结果相符。铊(Tl)同时可作为烟尘渣与土壤中相似元素和显著不同元素的检测指标。因此,我们建议铊(Tl)可作为硫铁矿焙烧烟尘渣的标志性元素,用于在粉尘识别中查找硫铁矿烟尘渣,并区分硫铁矿冶金粉尘和土壤粉尘。