四苯嗪的简明合成：通过氧化 C-H 活化的分子内氮杂-Prins 型环化反应。
A concise synthesis of tetrabenazine: an intramolecular aza-Prins-type cyclization via oxidative C-H activation.
机构信息
Department of Chemistry, College of Sciences, Kyung Hee University, 1 Hoegi-Dong, Seoul 130-701, Republic of Korea.
出版信息
Org Lett. 2011 Dec 16;13(24):6500-3. doi: 10.1021/ol202792q. Epub 2011 Nov 21.
PMID:22103629
Abstract
A concise synthesis of tetrabenazine and dihydrotetrabenazine is described. The key feature of this synthesis is the intramolecular aza-Prins-type cyclization of an amino allylsilane via oxidative C-H activation.
摘要
本文简述了四苯嗪和二氢四苯嗪的综合合成。此合成的关键特点在于通过氧化 C-H 活化，使氨烯丙基硅烷进行分子内氮杂-Prings 型环化反应。
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