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玻璃形成软球液体动力学的密度-温度-柔软度标度。

Density-temperature-softness scaling of the dynamics of glass-forming soft-sphere liquids.

机构信息

Instituto de Física Manuel Sandoval Vallarta, Universidad Autónoma de San Luis Potosí, Álvaro Obregón 64, 78000 San Luis Potosí, SLP, México.

出版信息

Phys Rev Lett. 2011 Oct 7;107(15):155701. doi: 10.1103/PhysRevLett.107.155701. Epub 2011 Oct 3.

Abstract

We employ the principle of dynamic equivalence between soft-sphere and hard-sphere fluids [Phys. Rev. E 68, 011405 (2003)] to describe the interplay of the effects of varying the density n, the temperature T, and the softness (characterized by a softness parameter ν(-1)) on the dynamics of glass-forming soft-sphere liquids in terms of simple scaling rules. The main prediction is the existence of a dynamic universality class associated with the hard-sphere fluid, constituted by the soft-sphere systems whose dynamic parameters depend on n, T, and ν only through the reduced density n*≡nσ(HS)(T*,ν). A number of scaling properties observed in recent experiments and simulations involving glass-forming fluids with repulsive short-range interactions are found to be a direct manifestation of this general dynamic equivalence principle.

摘要

我们采用软球和硬球流体之间的动态等效原理[Phys. Rev. E 68, 011405 (2003)],用简单的标度规则来描述密度 n、温度 T 和软度(由软度参数 ν(-1) 来描述)的变化对形成玻璃的软球液体动力学的影响之间的相互作用。主要的预测是存在一个与硬球流体相关的动态普遍性类别,由软球系统组成,其动力学参数仅通过 n*≡nσ(HS)(T*,ν) 依赖于 n、T 和 ν。最近涉及具有排斥短程相互作用的形成玻璃的流体的实验和模拟中观察到的许多标度性质,被发现是这种一般动态等效原理的直接体现。

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