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采用近红外光谱数据的偏最小二乘法分析和欧几里得距离法对茶样起源进行验证。

Validation of origins of tea samples using partial least squares analysis and Euclidean distance method with near-infrared spectroscopy data.

机构信息

Tea Research Institute, Nanjing Agricultural University, Nanjing 210095, China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2012 Feb;86:399-404. doi: 10.1016/j.saa.2011.10.056. Epub 2011 Nov 7.

Abstract

In today's global food markets, the ability to trace the origins of agricultural products is becoming increasingly important. We developed an efficient procedure for validating the authenticity and origin of tea samples where Partial Least Squares and Euclidean Distance methods, based on near-infrared spectroscopy data, were combined to classify tea samples from different tea producing areas. Four models for identification of authenticity of tea samples were constructed and utilized in our two-step procedure. High accuracy rates of 98.60%, 97.90%, 97.55%, and 99.83% for the calibration set, and 97.19%, 97.54%, 97.83%, 100% for test set, were achieved. After the first identification step, employing the four origin authenticity models, followed by the second step using the Euclidean Distance method, accuracy rates for specific origin identification were 98.43% in the calibration set and 96.84% in the test set. This method, employing two-step analysis of multi-origin model, accurately identified the origin of tea samples collected in four different areas. This study provided a potential reference method for the detection of "geographical indication" of agricultural products' and is available for use in traceability of origin studies.

摘要

在当今的全球食品市场中,追溯农产品产地的能力变得越来越重要。我们开发了一种有效的方法来验证茶叶样品的真实性和产地,该方法结合了偏最小二乘法和欧几里得距离方法,基于近红外光谱数据,用于对来自不同茶叶产区的茶叶样品进行分类。构建了四个用于鉴定茶叶样品真实性的模型,并在我们的两步程序中进行了利用。校准集的准确率分别达到了 98.60%、97.90%、97.55%和 99.83%,测试集的准确率分别达到了 97.19%、97.54%、97.83%和 100%。在经过第一次识别步骤,使用四个产地真实性模型后,再使用欧几里得距离方法进行第二步,在校准集和测试集的特定产地识别准确率分别为 98.43%和 96.84%。这种采用两步分析法和多产地模型的方法,可以准确地识别来自四个不同地区的茶叶样品的产地。本研究为农产品“地理标志”的检测提供了一种潜在的参考方法,可用于追溯农产品的产地。

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