利用自由基级联反应快速获得与石蒜科生物碱相关的多环吲哚啉。
Rapid access to polycyclic indolines related to the stephacidin alkaloids using a radical cascade.
机构信息
School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK.
出版信息
Chem Commun (Camb). 2012 Feb 14;48(14):1958-60. doi: 10.1039/c1cc16510k. Epub 2011 Dec 2.
PMID:22134634
Abstract
A new and very rapid access to indoline intermediates useful for the synthesis of alkaloids related to the stephacidins has been established using a radical cascade process initiated from a sulphur-substituted diketopiperazine.
摘要
建立了一种新的、非常快速的吲哚啉中间体的方法，该中间体可用于合成与石蚕碱相关的生物碱，该方法是通过一个由硫取代的二酮哌嗪引发的自由基级联反应实现的。
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