手性 2-萘甲酸/胺超分子有机荧光团的固态圆二色性和圆二色性荧光的非经典调谐。
Nonclassical tunability of solid-state CD and CPL properties of a chiral 2-naphthalenecarboxylic acid/amine supramolecular organic fluorophore.
机构信息
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
出版信息
Chem Asian J. 2012 Feb 6;7(2):360-6. doi: 10.1002/asia.201100727. Epub 2011 Dec 8.
PMID:22162330
Abstract
The solid-state chiral optical properties (circular dichroism and circularly polarized luminescence) of a 2-naphthalenecarboxylic acid/amine supramolecular organic fluorophore can be controlled by changing the aryl unit of the chiral 1-arylethylamine component of the molecule rather than altering the chirality of the 1-arylethylamine itself.
摘要
通过改变手性 1-芳基乙胺分子部分的芳基单元，而不是改变 1-芳基乙胺本身的手性，可以控制 2-萘甲酸/胺超分子有机荧光团的固态手性光学性质（圆二色性和圆偏振发光）。
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