Li Huiling, Du Huali, Gao Mingying, Chen Chanjuan, Lin Yinghe
Dept. of Stomatology, The Second People's Hospital of Zhuhai, Zhuhai 519020, China.
Hua Xi Kou Qiang Yi Xue Za Zhi. 2011 Oct;29(5):481-4.
The aim of this study was to investigate the korrosionsneigung of three metal specimens for casing removable denture by means of electrochemical method.
Three kinds of test specimens were prepared, including cobalt-chromium alloy, nickel-chrome alloy with titanium and pure titanium. Then they were analyzed via linear polarization in artificial saliva simulating oral environment. From this electrochemical test the polarization curves of these kinds of specimens were recorded. Then the scanning electron microscope (SEM) and X-ray diffractometer (XRD) were applied to assess the morphology and phase changes before and after electrochemical corrosion.
No typical Tafel curve had been recorded for pure titanium, other than cobalt-chromium alloy and nickel-chrome alloy with titanium. Nickel-chrome alloy with titanium got more negative corrosion potential and higher corrosion current than cobalt-chromium alloy. Via SEM, the obvious changes were observed on the morphology and phase before and after corrosion on cobalt-chromium and nickel-chrome alloy with titanium specimens while pure titanium having no change. The XRD provided us little changes on these all three materials.
The results confirm that the korrosionsneigung of the studied cobalt-chromium alloy in artificial saliva is lower than that nickel-chrome alloy with titanium. Pure titanium is the most stable one of the three materials and is extreme hard to be etched.
本研究旨在通过电化学方法研究三种可摘局部义齿基托金属标本的耐腐蚀倾向。
制备三种测试标本,包括钴铬合金、含钛镍铬合金和纯钛。然后在模拟口腔环境的人工唾液中通过线性极化对它们进行分析。通过该电化学测试记录这些标本的极化曲线。然后应用扫描电子显微镜(SEM)和X射线衍射仪(XRD)评估电化学腐蚀前后的形态和相变。
除钴铬合金和含钛镍铬合金外,未记录到纯钛的典型塔菲尔曲线。含钛镍铬合金比钴铬合金具有更负的腐蚀电位和更高的腐蚀电流。通过SEM观察到,钴铬合金和含钛镍铬合金标本腐蚀前后的形态和相有明显变化,而纯钛没有变化。XRD显示这三种材料几乎没有变化。
结果证实,所研究的钴铬合金在人工唾液中的耐腐蚀倾向低于含钛镍铬合金。纯钛是这三种材料中最稳定的,极难被腐蚀。