Key Laboratory for Special Functional Materials of the Ministry of Education, Henan University, Kaifeng, 475004, PR China.
Org Lett. 2012 Jan 6;14(1):248-51. doi: 10.1021/ol2030229. Epub 2011 Dec 19.
Mono- and di-AcO substituted BODIPYs (1 and 2) were synthesized from TM-BDP. The structures of 1 and 2 were supported by single crystal X-ray analysis. Both 1 and 2 possess a large absorption coefficient, high fluorescence quantum yield, and high light stability. Compound 2 has much improved water solubility which is highly desirable for biological applications. Theoretical calculation supports our observations in X-ray analysis, absorption, and cyclic voltammetry.
单取代和双取代的 BODIPY（1 和 2）是由 TM-BDP 合成的。通过单晶 X 射线分析证实了 1 和 2 的结构。1 和 2 都具有较大的吸收系数、高荧光量子产率和高光稳定性。化合物 2 的水溶性有了很大的提高，这对生物应用非常理想。理论计算支持了我们在 X 射线分析、吸收和循环伏安法方面的观察结果。
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