Sc3C2@C80 双加成富勒吡咯里啶的制备及 ESR 研究。

Preparation and ESR study of Sc3C2@C80 bis-addition fulleropyrrolidines.

机构信息

Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing, China.

出版信息

Dalton Trans. 2012 Mar 7;41(9):2567-70. doi: 10.1039/c2dt12162j. Epub 2012 Jan 6.

DOI:10.1039/c2dt12162j

PMID:22228172

Abstract

The bis-adducts of Sc(3)C(2)@C(80) fulleropyrrolidines were prepared and isolated. ESR study showed that these bis-addition fulleropyrrolidines have varied paramagnetism resulting from diverse reaction sites for the second pyrrolidine addend.

摘要

Sc(3)C(2)@C(80)富勒吡咯烷的双加成产物被制备和分离。ESR 研究表明，这些双加成富勒吡咯烷具有不同的顺磁性，这是由于第二个吡咯烷加合物的不同反应位点所致。