Department of Chemistry, University of Science & Technology of China, Hefei, 230026 China.
Phys Chem Chem Phys. 2012 Feb 14;14(6):1978-84. doi: 10.1039/c2cp23402e. Epub 2012 Jan 10.
Urine pretreatment has attracted increasing interest as it is able to relieve the nitrogen and phosphorus overloading problems in municipal wastewater treatment plants. In this study, an integrated process, which combines magnesium ammonium phosphate (MAP) precipitation with a microbial fuel cell (MFC), is proposed for the recovery of a slow-release fertilizer and electricity from urine. In such a two-step process, both nitrogen and phosphorus are recovered through the MAP process, and organic matters in the urine are converted into electricity in the MFCs. With this integrated process, when the phosphorus recovery is maximized without a dose of PO(4)(3-)-P in the MAP precipitation process, removal efficiencies for PO(4)(3)-P and NH(4)(+)-N of 94.6% and 28.6%, respectively, were achieved with a chemical oxygen demand (COD) of 64.9% accompanied by a power output of 2.6 W m(-3). Whereas removal efficiencies for PO(4)(3)-P and NH(4)(+)-N of 42.6% and 40%, respectively, and a COD of 62.4% and power density of 0.9 W m(-3) were obtained if simultaneous recovery of phosphorus and nitrogen was required through dosing with 620 mg L(-1) of PO(4)(3-)-P in the MAP process. This work provides a new sustainable approach for the efficient and cost-effective treatment of urine with the recovery of energy and resources.
尿液预处理作为一种能够缓解城市污水处理厂氮磷过负荷问题的方法,引起了越来越多的关注。在这项研究中,提出了一种将鸟粪石(MAP)沉淀与微生物燃料电池(MFC)相结合的集成工艺,用于从尿液中回收缓释肥料和电能。在这个两步过程中,通过 MAP 工艺回收氮和磷,而尿液中的有机物则在 MFC 中转化为电能。在这种集成工艺中,当 MAP 沉淀过程中不添加 PO(4)(3-)-P 时,磷的回收达到最大化,此时 PO(4)(3-)-P 和 NH(4)(+)-N 的去除效率分别为 94.6%和 28.6%,化学需氧量(COD)为 64.9%,同时产生 2.6 W m(-3)的功率。而如果需要通过在 MAP 过程中投加 620 mg L(-1)的 PO(4)(3-)-P 来同时回收磷和氮,则 PO(4)(3-)-P 和 NH(4)(+)-N 的去除效率分别为 42.6%和 40%,COD 为 62.4%,功率密度为 0.9 W m(-3)。这项工作为高效、经济地处理尿液并回收能源和资源提供了一种新的可持续方法。