一种稳定的锆 N-杂环卡宾配合物，用于活性和高立体选择性开环聚合 rac-丙交酯。
A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide.
机构信息
Laboratoire DECOMET, Institut de Chimie de Strasbourg, CNRS-Université de Strasbourg, 1 rue Blaise Pascal, 67000 Strasbourg, France.
出版信息
Chem Commun (Camb). 2012 Feb 21;48(16):2213-5. doi: 10.1039/c2cc16819g. Epub 2012 Jan 17.
PMID:22252312
Abstract
A readily accessible and robust Zr-NHC complex was found to polymerize rac-lactide in a highly controlled, living and stereoselective manner to afford heterotactic PLA.
摘要
研究发现，一种易于获得且稳定的 Zr-NHC 配合物可以高度可控、立体选择性地聚合 rac-丙交酯，得到立构规整 PLA。
Zotero 插件