Gebavi Hrvoje, Taccheo Stefano, Milanese Daniel, Monteville Achille, Le Goffic Olivier, Landais David, Mechin David, Tregoat Denis, Cadier Benoit, Robin Thierry
College of Engineering, Swansea University, Singleton Park, Swansea, UK.
Opt Express. 2011 Dec 5;19(25):25077-83. doi: 10.1364/OE.19.025077.
The present work describes photodarkening from the viewpoint of cooperative luminescence. The temporal evolution of both effects was measured simultaneously by means of ytterbium doped aluminosilicate fibers for concentrations up to 1.8 wt% Yb3+. The quadratic dependence of photodarkening and cooperative luminescence versus dopant concentration was observed. The change in the photodarkening and cooperative luminescence mutual dynamics for highly and low doped fibers is ascribed to a different ion number which forms the cluster. Cooperative luminescence is proved to be a natural probe for photodarkening since it provides new pieces of information and contributes to the photodarkening mechanism description.
本工作从协同发光的角度描述了光暗化现象。通过镱掺杂铝硅酸盐光纤,同时测量了浓度高达1.8 wt% Yb3+时这两种效应的时间演化。观察到光暗化和协同发光对掺杂剂浓度的二次依赖性。高掺杂和低掺杂光纤的光暗化和协同发光相互动力学的变化归因于形成团簇的离子数不同。协同发光被证明是光暗化的天然探针,因为它提供了新的信息,并有助于描述光暗化机制。