He Guang-Xiu, Zhang Zhi-Huan, Peng Xu-Yang, Zhu Lei, Lu Ling
Colleges of Geosciences, China University of Petroleum, Beijing 102249, China.
Huan Jing Ke Xue. 2011 Nov;32(11):3284-93.
62 surface soil samples were collected from different environmental function zones in Beijing. Sulfur and oxygen heterocyclic aromatic compounds were detected by GC/MS. The objectives of this study were to identify the composition and distribution of these compounds, and discuss their sources. The results showed that the oxygen and sulfur heterocyclic aromatic compounds in the surface soils mainly contained dibenzofuran, methyl- and C2-dibenzofuran series, dibenzothiophene, methyl-, C2- and C3-dibenzothiophene series and benzonaphthothiophene series. The composition and distribution of the oxygen and sulfur heterocyclic aromatic compounds in the surface soil samples varied in the different environmental function zones, of which some factories and the urban area received oxygen and sulfur heterocyclic aromatic compounds most seriously. In Beijing, the degree of contamination by oxygen and sulfur heterocyclic aromatic compounds in the north surface soil was higher than that in the south. There were preferable linear correlations between the concentration of dibenzofuran series and fluorene series, as well as the concentration of dibenzothiophene series and dibenzofuran series. The oxygen and sulfur heterocyclic aromatic compounds in the surface soil were mainly derived from combustion products of oil and coal and direct input of mineral oil, etc. There were some variations in pollution sources of different environmental function zones.
从北京不同环境功能区采集了62个表层土壤样本。采用气相色谱/质谱联用仪检测了硫和氧杂环芳烃化合物。本研究的目的是确定这些化合物的组成和分布,并探讨其来源。结果表明,表层土壤中的氧和硫杂环芳烃化合物主要包括二苯并呋喃、甲基和C2 - 二苯并呋喃系列、二苯并噻吩、甲基、C2和C3 - 二苯并噻吩系列以及苯并萘并噻吩系列。表层土壤样本中氧和硫杂环芳烃化合物的组成和分布在不同环境功能区存在差异,其中一些工厂和市区受到氧和硫杂环芳烃化合物的污染最为严重。在北京,北部表层土壤中氧和硫杂环芳烃化合物的污染程度高于南部。二苯并呋喃系列与芴系列的浓度之间以及二苯并噻吩系列与二苯并呋喃系列的浓度之间存在较好的线性相关性。表层土壤中的氧和硫杂环芳烃化合物主要来源于石油和煤炭的燃烧产物以及矿物油的直接输入等。不同环境功能区的污染源存在一些差异。