高产合成中性和羰基富端芳基硼烯配合物。
High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex.
机构信息
Institut für Anorganische Chemie, Julius-Maximilians-Universität, Würzburg, Am Hubland, D-97074, Würzburg, Germany.
出版信息
Chem Commun (Camb). 2012 Mar 11;48(21):2701-3. doi: 10.1039/c2cc17445f. Epub 2012 Feb 3.
PMID:22301941
Abstract
High yield synthesis of trans-[(Me(3)P)(OC)(3)Fe = BDur] (Dur, "Duryl" = 2,3,4,6-Me(4)C(6)H) is achieved by salt elimination and subsequent liberation of trimethylsilylbromide from K[Fe(CO)(3)(PMe(3))SiMe(3)] and Br(2)BDur.
摘要
高产合成反式-[(Me(3)P)(OC)(3)Fe = BDur]（Dur，“Duryl”= 2,3,4,6-Me(4)C(6)H）是通过盐消除和随后从 K[Fe(CO)(3)(PMe(3))SiMe(3)]和 Br(2)BDur 中释放三甲基溴化硅来实现的。
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