Alieva Rafiqa A, Mardanova Vusala I, Chyraqov Famil M, Gurbanov Atash V, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m127. doi: 10.1107/S1600536811056200. Epub 2012 Jan 11.
In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl-ate O atoms, pyridine N atoms and two water mol-ecules in an elongated octa-hedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intra-molecular O-H⋯O and N-H⋯O hydrogen bonding is observed. The water mol-ecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxyl-ate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio.
在标题化合物[Cu(C₁₂H₁₁N₂O₄)₂(C₁₀H₁₄N₂O)₂(H₂O)₂]中,Cu(II)原子位于对称中心,以拉长的八面体几何构型由羧酸根O原子、吡啶N原子和两个水分子配位。吡啶环相对于苯环的二面角为74.83 (12)°。观察到分子内的O—H⋯O和N—H⋯O氢键。水分子是相邻羧酸根基团羰基O原子的氢键供体,形成了沿a轴延伸的链。其中一个乙基在两组位置上无序,比例为0.787 (5):0.213。