Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Phys Chem Chem Phys. 2012 May 7;14(17):5891-901. doi: 10.1039/c2cp40080d. Epub 2012 Feb 24.
Surface-Enhanced Raman Scattering (SERS) spectroscopy has experienced a rapid growth over the past 30 years, and has become a valuable tool in various research areas. In conjunction with recent explosive development of nanoscience and nanotechnology, the SERS-active substrates have also expanded from traditional Group 11 metals (Au, Ag, Cu) to non-Group 11 nanostructures. This paper gives an overview of historical advances in the use of non-Group 11 nanostructures as substrates for SERS. Several possible mechanisms and important factors for SERS from non-Group 11 nanostructures are discussed in detail. The SERS from non-Group 11 nanostructures provides many significant applications in surface, interface analysis and biochemical detection. It is reasonable to believe that the advancement in the non-Group 11 nanostructures-based SERS-active substrates will lead to a more promising future for the SERS technology in surface science, spectroscopy and biomedicine.
表面增强拉曼散射(SERS)光谱学在过去 30 年中经历了快速发展,已成为各个研究领域中非常有价值的工具。随着纳米科学和纳米技术的爆炸式发展,SERS 活性衬底也从传统的第 11 族金属(金、银、铜)扩展到了非第 11 族纳米结构。本文概述了将非第 11 族纳米结构用作 SERS 衬底的历史进展。详细讨论了非第 11 族纳米结构产生 SERS 的几种可能机制和重要因素。非第 11 族纳米结构的 SERS 在表面、界面分析和生物化学检测中具有许多重要的应用。可以合理地认为,基于非第 11 族纳米结构的 SERS 活性衬底的进步将为表面科学、光谱学和生物医学中的 SERS 技术带来更广阔的前景。