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过渡金属和半导体纳米结构的表面增强拉曼散射(SERS)。

Surface-Enhanced Raman Scattering (SERS) on transition metal and semiconductor nanostructures.

机构信息

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

出版信息

Phys Chem Chem Phys. 2012 May 7;14(17):5891-901. doi: 10.1039/c2cp40080d. Epub 2012 Feb 24.

Abstract

Surface-Enhanced Raman Scattering (SERS) spectroscopy has experienced a rapid growth over the past 30 years, and has become a valuable tool in various research areas. In conjunction with recent explosive development of nanoscience and nanotechnology, the SERS-active substrates have also expanded from traditional Group 11 metals (Au, Ag, Cu) to non-Group 11 nanostructures. This paper gives an overview of historical advances in the use of non-Group 11 nanostructures as substrates for SERS. Several possible mechanisms and important factors for SERS from non-Group 11 nanostructures are discussed in detail. The SERS from non-Group 11 nanostructures provides many significant applications in surface, interface analysis and biochemical detection. It is reasonable to believe that the advancement in the non-Group 11 nanostructures-based SERS-active substrates will lead to a more promising future for the SERS technology in surface science, spectroscopy and biomedicine.

摘要

表面增强拉曼散射(SERS)光谱学在过去 30 年中经历了快速发展,已成为各个研究领域中非常有价值的工具。随着纳米科学和纳米技术的爆炸式发展,SERS 活性衬底也从传统的第 11 族金属(金、银、铜)扩展到了非第 11 族纳米结构。本文概述了将非第 11 族纳米结构用作 SERS 衬底的历史进展。详细讨论了非第 11 族纳米结构产生 SERS 的几种可能机制和重要因素。非第 11 族纳米结构的 SERS 在表面、界面分析和生物化学检测中具有许多重要的应用。可以合理地认为,基于非第 11 族纳米结构的 SERS 活性衬底的进步将为表面科学、光谱学和生物医学中的 SERS 技术带来更广阔的前景。

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