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用 K2CO3 活化木屑微波加热制备中孔活性炭。

Mesoporous activated carbon from wood sawdust by K2CO3 activation using microwave heating.

机构信息

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.

出版信息

Bioresour Technol. 2012 May;111:425-32. doi: 10.1016/j.biortech.2012.01.141. Epub 2012 Feb 2.

Abstract

Wood sawdust was converted into a high-quality activated carbon (WSAC) via microwave-induced K(2)CO(3) activation. The operational variables including chemical impregnation ratio, microwave power and irradiation time on the carbon yield and adsorption capability were identified. The surface physical characteristics of WSAC were examined by pore structural analysis, scanning electron microscopy and nitrogen adsorption isotherms. The adsorptive behavior of WSAC was quantified using methylene blue as model dye compound. The best conditions resulted in activated carbon with a monolayer adsorption capacity of 423.17 mg/g and carbon yield of 80.75%. The BET surface area, Langmuir surface area and total pore volume were corresponded to 1496.05 m(2)/g, 2245.53 m(2)/g and 0.864 cm(3)/g, respectively. The findings support the potential to prepare high surface area and mesoporous activated carbon from wood sawdust by microwave assisted chemical activation.

摘要

木屑经微波诱导 K2CO3 活化转化为高品质活性炭(WSAC)。确定了化学浸渍比、微波功率和辐照时间等操作变量对产碳率和吸附性能的影响。通过孔隙结构分析、扫描电子显微镜和氮气吸附等温线对 WSAC 的表面物理特性进行了研究。采用亚甲基蓝作为模型染料化合物对 WSAC 的吸附行为进行了定量分析。最佳条件下制得的活性炭的单层吸附容量为 423.17mg/g,产碳率为 80.75%。BET 比表面积、Langmuir 比表面积和总孔体积分别对应为 1496.05m2/g、2245.53m2/g 和 0.864cm3/g。研究结果表明,通过微波辅助化学活化法从木屑中制备高比表面积和中孔活性炭具有潜力。

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