笼中氰化物。
A caged cyanide.
机构信息
Max-Planck-Institut für Bioanorganische Chemie, Stifstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany.
出版信息
Photochem Photobiol Sci. 2012 Apr;11(4):620-2. doi: 10.1039/c2pp05359d. Epub 2012 Mar 12.
PMID:22406687
Abstract
A photoactivatable caged cyanide, 1-(2-nitrophenyl)ethyl (NPE) cyanide, was synthesized, which upon irradiation in the near UV releases cyanide. It is demonstrated that the compound can be used to induce formation of the Fe(III)-CN(-) complex in the heme protein nitrophorin 4 from Rhodnius prolixus.
摘要
一种光活化的笼状氰化物 1-(2-硝基苯基)乙基(NPE)氰化物被合成出来，它在近紫外光照射下释放氰化物。实验证明，该化合物可用于诱导来自丽蝇的血影蛋白硝酸还原酶 4 中形成 Fe(III)-CN(-)配合物。
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