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一些地下水和地表水中成分对芬顿反应降解 4-氯苯酚的影响。

Influence of some groundwater and surface waters constituents on the degradation of 4-chlorophenol by the fenton reaction.

机构信息

Department of Chemistry, University of Waterloo, Waterloo, Ont. Canada.

出版信息

Chemosphere. 1995 Jan;30(1):9-20. doi: 10.1016/0045-6535(94)00371-z.

DOI:10.1016/0045-6535(94)00371-z
PMID:22454978
Abstract

The Fenton reaction has been applied to the degradation of 4-chlorophenol in aqueous solutions containing various anions. The rate of the reaction was found to decrease in the following order of anions (at the same concentrations): CIO (4) ~ NO (3)- > SO(4) (2-) > CI(-)> >HPO(4) (2-) > HCO(3)(-). Degradation of the pollutant containing the above anions at concentrations typical of those found in groundwater and surface waters was affected in a similar way. The results are discussed in terms of the effects of these anions on the rates of the oxidation of ferrous anion as well as on their role in the scavenging of hydroxyl radical

摘要

芬顿反应已应用于降解含有各种阴离子的水溶液中的 4-氯苯酚。发现反应速率按以下阴离子顺序降低(在相同浓度下):CIO(4)- > NO(3)- > SO(4) (2-) > CI- > > HPO(4) (2-) > HCO(3)-。以地下水中和地表水中常见浓度存在的上述阴离子的污染物的降解受到类似的影响。结果根据这些阴离子对亚铁阴离子氧化速率的影响及其在羟基自由基清除中的作用进行了讨论。

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