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还原氧化石墨烯/氧化锌复合材料:用于污染物管理的可重复使用吸附剂。

Reduced graphene oxide/ZnO composite: reusable adsorbent for pollutant management.

机构信息

Institute for Frontier Materials, Deakin University , Geelong, Victoria, Australia 3217.

出版信息

ACS Appl Mater Interfaces. 2012 Jun 27;4(6):3084-90. doi: 10.1021/am300445f. Epub 2012 Jun 15.

Abstract

Reduced graphene oxide (RGO) coated with ZnO nanoparticles (NPs) was synthesized by a self-assembly and in situ photoreduction method, and then their application for removing organic pollutant from water was investigated. The RGO@ZnO composite nanomaterial has unique structural features including well-dispersed NPs on the surface and dense NPs loading. This composite exhibited a greatly improved Rhodamine B (RhB) adsorption capacity and an improved photocatalytic activity for degrading RhB compared to neat ZnO NPs. These properties made RGO@ZnO reusable for pollutant adsorbent. The composite showed an excellent cycling performance for organic pollutant removal up to 99% recovery over several cycles via simulated sunlight irradiation.

摘要

通过自组装和原位光还原法合成了负载氧化锌纳米粒子(NPs)的还原氧化石墨烯(RGO),并研究了其在去除水中有机污染物方面的应用。RGO@ZnO 复合材料具有独特的结构特征,包括 NPs 在表面的良好分散和 NPs 的密集负载。与纯 ZnO NPs 相比,该复合材料对罗丹明 B(RhB)的吸附能力显著提高,光催化降解 RhB 的活性也得到提高。这些特性使 RGO@ZnO 成为一种可重复使用的污染物吸附剂。该复合材料在模拟太阳光照射下,通过几个循环的吸附-脱附实验,对有机污染物的去除率高达 99%,表现出了优异的循环性能。

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