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液体在纳米结构表面的滑动。

Liquid slip on a nanostructured surface.

机构信息

Research Institute of Advanced Materials, Department of Materials Science and Engineering, Seoul National University, Daehak-Dong, Gwanak-Gu, Seoul, 151- 744, Korea.

出版信息

Langmuir. 2012 Jul 17;28(28):10488-94. doi: 10.1021/la302264t. Epub 2012 Jul 5.

Abstract

We explored a liquid slip, referred to as the Navier slip, at liquid-solid interface. Such a slip is provoked by the physicochemical features of the liquid-solid system. The goal of this study was to investigate the effect of a nanoengineered surface structure on liquid slip by fabricating the self-assembly structure of nano Zinc oxide (n-ZnO). We have also examined how the liquid-solid surface interaction controlled by hydrophobic chemical treatment affects the liquid slip. The findings showed that liquid slip increases with decreasing the characteristic length scales (e.g., channel height and depth), resulting in drag reduction. It was also found that dewetted (Cassie) state due to the generation of air gap developed by n-ZnO was more critical for the liquid slip than the minimization of interface interaction. The linear and nonlinear Navier slip models showed that liquid slip behavior is more obvious when increasing the nonlinearity. This study will contribute to understanding of the underlying physics behind fluid slip phenomena, such as the Navier slip for Newtonian liquids and Maxwell's slip for Newtonian gases.

摘要

我们探究了一种在固液界面存在的液体滑移,称之为纳维滑移。这种滑移是由固液系统的物理化学特性引起的。本研究的目的是通过制备纳米氧化锌(n-ZnO)的自组装结构,来研究纳米工程表面结构对液体滑移的影响。我们还研究了疏水化学处理控制的固液表面相互作用如何影响液体滑移。研究结果表明,液体滑移随特征长度尺度(例如通道高度和深度)的减小而增加,从而导致阻力减小。还发现,由于 n-ZnO 产生的气隙,形成了非润湿(Cassie)状态,这对液体滑移比界面相互作用的最小化更为关键。线性和非线性纳维滑移模型表明,随着非线性的增加,液体滑移行为更为明显。本研究将有助于理解流体滑移现象背后的物理机制,如牛顿液体的纳维滑移和牛顿气体的麦克斯韦滑移。

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