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电泳沉积法制备 Al2O3/SiC/ZrO2 功能梯度材料及其力学性能

Fabrication and mechanical properties of Al2O3/SiC/ZrO2 functionally graded material by electrophoretic deposition.

机构信息

Department of Mechanical Engineering and Advanced Material Research Center, University of Malaya, 50603, Kuala Lumpur, Malaysia.

出版信息

J Mech Behav Biomed Mater. 2012 Aug;12:144-50. doi: 10.1016/j.jmbbm.2012.02.029. Epub 2012 Apr 20.

Abstract

This study describes the synthesis of Al(2)O(3)/SiC/ZrO(2) functionally graded material (FGM) in bio-implants (artificial joints) by electrophoretic deposition (EPD). A suitable suspension that was based on 2-butanone was applied for the EPD of Al(2)O(3)/SiC/ZrO(2), and a pressureless sintering process was applied as a presintering. Hot isostatic pressing (HIP) was used to densify the deposit, with beneficial mechanical properties after 2 h at 1800 °C in Ar atmosphere. The maximum hardness in the outer layer (90 vol.% Al(2)O(3)+10 vol.% SiC) and maximum fracture toughness in the core layer (75 vol.% Al(2)O(3)+10 vol.% SiC + 15 vol.% ZrO(2)) composite were 20.8±0.3 GPa and 8±0.1 MPa m(1/2), respectively. The results, when compared with results from Al(2)O(3)/ZrO(2) FGM, showed that SiC increased the compressive stresses in the outer layers, while the inner layers were under a residual tensile stress.

摘要

本研究通过电泳沉积(EPD)法在生物植入物(人工关节)中合成了 Al(2)O(3)/SiC/ZrO(2) 功能梯度材料(FGM)。采用基于 2-丁酮的合适悬浮液进行了 Al(2)O(3)/SiC/ZrO(2) 的 EPD,然后采用无压烧结工艺作为预烧结。热等静压(HIP)用于致密化沉积物,在 Ar 气氛中 1800°C 下保温 2 小时后,可获得有益的机械性能。外层(90vol.%Al(2)O(3)+10vol.%SiC)的最大硬度和芯层(75vol.%Al(2)O(3)+10vol.%SiC+15vol.%ZrO(2))的最大断裂韧性分别为 20.8±0.3GPa 和 8±0.1MPa m(1/2)。与 Al(2)O(3)/ZrO(2)FGM 的结果相比,结果表明 SiC 增加了外层的压缩应力,而内层则处于残余拉伸应力之下。

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