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非平衡涨落动力学中的熵产生。

Entropy production in non-equilibrium fluctuating hydrodynamics.

机构信息

CNR-ISC and Dipartimento di Fisica, Università Sapienza - p.le A. Moro 2, 00185 Roma, Italy.

出版信息

J Chem Phys. 2012 Jul 7;137(1):014509. doi: 10.1063/1.4731633.

Abstract

Fluctuating entropy production is studied for a set of linearly coupled complex fields. The general result is applied to non-equilibrium fluctuating hydrodynamic equations for coarse-grained fields (density, temperature, and velocity), in the framework of model granular fluids. We find that the average entropy production, obtained from the microscopic stochastic description, can be expressed in terms of macroscopic quantities, in analogy with linear non-equilibrium thermodynamics. We consider the specific cases of driven granular fluids with two different kinds of thermostat and the homogeneous cooling regime. In all cases, the average entropy production turns out to be the product of a thermodynamic force and a current: the former depends on the specific energy injection mechanism, the latter takes always the form of a static correlation between fluctuations of density and temperature time-derivative. Both vanish in the elastic limit. The behavior of the entropy production is studied at different length scales and the qualitative differences arising for the different granular models are discussed.

摘要

波动的熵产生被研究了一组线性耦合的复场。一般的结果被应用于非平衡波动的粗粒场(密度、温度和速度)的流体动力学方程,在模型颗粒流体的框架中。我们发现,从微观随机描述中得到的平均熵产生,可以用宏观量来表示,类似于线性非平衡热力学。我们考虑了具有两种不同的温度调节和均匀冷却的驱动颗粒流体的具体情况。在所有情况下,平均熵产生都是热力学力和电流的乘积:前者取决于特定的能量注入机制,后者总是密度和温度时间导数的波动之间的静态相关。两者在弹性极限时都为零。在不同的长度尺度上研究了熵产生的行为,并讨论了不同颗粒模型的出现的定性差异。

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