半导体碳纳米管和共价有机多面体-C60 纳米杂化物用于光收集。
Semiconducting carbon nanotube and covalent organic polyhedron-C60 nanohybrids for light harvesting.
机构信息
Department of Chemistry, University of Kansas, Lawrence, KS 66045, USA.
出版信息
Chem Commun (Camb). 2012 Aug 28;48(67):8377-9. doi: 10.1039/c2cc33517d. Epub 2012 Jul 16.
PMID:22796747
Abstract
We demonstrate noncovalent electrostatic and π-π interactions to assemble semiconducting single wall carbon nanotube (SWCNT)-C(60)@COP nanohybrids. The C(60)@COP light harvesting complexes bind strongly to SWCNTs due to significant π-π-stacking between C(60), the aromatic dicarbazolylacetylene moieties and the nanotube surfaces.
摘要
我们展示了非共价静电和π-π相互作用来组装半导体单壁碳纳米管（SWCNT）-C（60）@COP 纳米杂化物。由于 C（60）、芳香二咔唑基乙炔部分和纳米管表面之间存在显著的π-π堆积，C（60）@COP 光收集复合物与 SWCNT 结合非常牢固。
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