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(E,E)-1,2-双[3-(丙-2-炔-1-基氧基)亚苄基]肼

(E,E)-1,2-Bis[3-(prop-2-yn-1-yl-oxy)benzyl-idene]hydrazine.

作者信息

Al-Mehana Wisam Naji Atiyah, Yahya Rosiyah, Sonsudin Faridah, Lo Kong Mun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2087. doi: 10.1107/S1600536812025524. Epub 2012 Jun 13.

Abstract

The mol-ecule of the title compound, C(20)H(16)N(2)O(2), is centrosymmetric, the inversion center being located at the mid-point of the central azine bond. The conformation around the C=N bond is E. The whole mol-ecule (except for the H atoms) is essentially planar, with an r.m.s. deviation of 0.07 Å. In the crystal, mol-ecules are linked head-to-tail by pairs of C-H⋯O hydrogen bonds, forming inversion dimers, and resulting in the formation of chains propagating along [011].

摘要

标题化合物C(20)H(16)N(2)O(2)的分子是中心对称的,反演中心位于中央嗪键的中点。C=N键周围的构象为E型。整个分子(除氢原子外)基本呈平面状,均方根偏差为0.07 Å。在晶体中,分子通过C-H⋯O氢键对首尾相连,形成反演二聚体,并导致形成沿[011]方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a19d/3393903/c8aaa8b44916/e-68-o2087-fig1.jpg

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