2-{(E)-[(3-碘-4-甲基苯基)亚氨基]甲基}-4-(三氟甲氧基)苯酚
2-{(E)-[(3-Iodo-4-methyl-phen-yl)imino]-meth-yl}-4-(trifluoro-meth-oxy)phenol.
作者信息
Pekdemir Merve, Işık Samil, Alaman Ağar Ayşen
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2148. doi: 10.1107/S1600536812026876. Epub 2012 Jun 20.
The title compound, C(15)H(11)F(3)INO(2), adopts the enol-imine tautomeric form. The mol-ecule displays an E conformation with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 12.4 (2)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. The trifluoro-meth-oxy-phenyl group is disordered over two sites with an occupancy ratio of 0.621 (6):0.379 (6). The crystal structure features C-H⋯π inter-actions.
标题化合物C(15)H(11)F(3)INO(2) 采取烯醇 - 亚胺互变异构形式。分子相对于亚胺C=N双键呈E构象。两个苯环之间的二面角为12.4 (2)°。分子构象通过分子内O - H⋯N氢键得以稳定，该氢键形成一个S(6)环模式。三氟甲氧基苯基在两个位置上无序，占有率为0.621 (6):0.379 (6)。晶体结构具有C - H⋯π相互作用。
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