由N,N,N-三齿双（咪唑烷）吡啶（PyBidine）-Cu(OTf)₂络合物催化的磺酰亚胺与亚胺酯的顺式选择性不对称曼尼希反应。 - Suppr

syn-Selective asymmetric Mannich reaction of sulfonyl imines with iminoesters catalyzed by the N,N,N-tridentate bis(imidazolidine)pyridine (PyBidine)-Cu(OTf)2 complex.

作者信息

Arai Takayoshi, Mishiro Asami, Matsumura Eri, Awata Atsuko, Shirasugi Mayu

机构信息

Department of Chemistry, Graduate School of Science, Chiba University, Inage, Chiba 263-8522, Japan.

出版信息

Chemistry. 2012 Sep 3;18(36):11219-22. doi: 10.1002/chem.201201537. Epub 2012 Jul 24.

DOI:10.1002/chem.201201537

PMID:22829410

Abstract

摘要

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syn-Selective asymmetric Mannich reaction of sulfonyl imines with iminoesters catalyzed by the N,N,N-tridentate bis(imidazolidine)pyridine (PyBidine)-Cu(OTf)2 complex.

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syn-Selective asymmetric Mannich reaction of sulfonyl imines with iminoesters catalyzed by the N,N,N-tridentate bis(imidazolidine)pyridine (PyBidine)-Cu(OTf)2 complex.

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