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新型两性秸秆基吸附剂从水溶液中高效去除阳离子和阴离子染料。

Efficient removal of both cationic and anionic dyes from aqueous solutions using a novel amphoteric straw-based adsorbent.

机构信息

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210093, PR China.

出版信息

Carbohydr Polym. 2012 Oct 1;90(2):887-93. doi: 10.1016/j.carbpol.2012.06.015. Epub 2012 Jun 17.

Abstract

In the current paper, a novel amphoteric straw-based adsorbent was prepared and applied to adsorb various dyes from aqueous solutions. The amphoteric adsorbent was proven effective in eliminating both cationic and anionic dyes (methylene blue and acid green 25), especially at corresponding favored pH conditions. The fundamental adsorption behavior of the adsorbent on removing various dyes was also investigated at different temperatures. The adsorption isotherms were all best-fitted by the Langmuir equation, whereas the adsorption kinetics was well-described by both the pseudo-second order model and the Elovich model. The experimental result revealed that the adsorption mechanism followed the monolayer chemical adsorption with an ion-exchange process.

摘要

在本论文中,制备了一种新型两性秸秆基吸附剂,并将其应用于从水溶液中吸附各种染料。实验证明,该两性吸附剂能有效去除阳离子染料(亚甲基蓝)和阴离子染料(酸性绿 25),特别是在相应的有利 pH 条件下。此外,还在不同温度下研究了吸附剂对各种染料去除的基本吸附行为。吸附等温线均能较好地拟合朗缪尔方程,而吸附动力学则能同时被准二级模型和 Elovich 模型很好地描述。实验结果表明,吸附机制遵循离子交换过程的单层化学吸附。

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