Lee Seok Jae, Koo Ja Ryong, Shin Hyunsu, Han Wone Keun, Lee Kum Hee, Yoon Seung Soo, Kim Young Kwan
Department of Information Display, Hongik University, Seoul, 121-791, Korea.
J Nanosci Nanotechnol. 2012 May;12(5):4154-8. doi: 10.1166/jnn.2012.5917.
We have demonstrated lower driving voltage and efficient blue phosphorescent organic light emitting diodes (PHOLEDs) using iridium(III) bis[(4,6-di-fluoropheny)-pyridinato-N,C2] picolinate (Flrpic) doped in new host material 9-(4-(triphenylsilyl)phenyl)-9H-carbazole (SPC) and 2,2',2"-(1,3,5-benzenetryl)tris(1-phenyl)-1H-benzimidazol (TPBi) as double-emitting layer (D-EML) system. The D-EML was employed to have good electron transportability and exciton confinement. Additionally, we fabricated white organic light-emitting diode (WOLED) using a phosphorescent red emitter; bis(2-phenylquinolinato)-acetylacetonate iridium III (Ir(pq)2acac) doped in SPC and TPBi as D-EML. The properties of white device exhibited a maximum luminous efficiency of 19.03 cd/A, a maximum external quantum efficiency of 9.91%, and a maximum power efficiency of 12.30 lm/W. It also showed white emission with CIE(x,y) coordinates of (x = 0.38, y = 0.37) at 8 V.
我们展示了使用掺杂在新型主体材料9-(4-(三苯基硅基)苯基)-9H-咔唑(SPC)和2,2',2"-(1,3,5-苯三基)三(1-苯基)-1H-苯并咪唑(TPBi)中的铱(III)双[(4,6-二氟苯基)-吡啶基-N,C2]吡啶甲酸酯(Flrpic)作为双发射层(D-EML)系统的较低驱动电压和高效蓝色磷光有机发光二极管(PHOLED)。采用D-EML以具有良好的电子传输性和激子限制。此外,我们使用磷光红色发射体制造了白色有机发光二极管(WOLED);掺杂在SPC和TPBi中的双(2-苯基喹啉基)-乙酰丙酮铱III(Ir(pq)2acac)作为D-EML。白色器件的性能表现出最大发光效率为19.03 cd/A,最大外量子效率为9.91%,最大功率效率为12.30 lm/W。在8 V时,它还显示出CIE(x,y)坐标为(x = 0.38, y = 0.37)的白色发射。