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以碳纳米管作为阳极材料的无介体微生物燃料电池的构建与性能评估

Construction and performance evaluation of mediator-less microbial fuel cell using carbon nanotubes as an anode material.

作者信息

Roh Sung-Hee, Kim Sun-Il

机构信息

Department of Chemical and Biochemical Engineering, Chosun University, Gwangju 501-759, Korea.

出版信息

J Nanosci Nanotechnol. 2012 May;12(5):4252-5. doi: 10.1166/jnn.2012.5931.

Abstract

A microbial fuel cell (MFC) is a device that converts chemical energy to electrical energy using the catalytic reaction of microorganisms. We investigated the performance of mediator-less MFC with carbon nanotubes (CNTs)/graphite felt composite electrodes. The addition of CNTs to a graphite felt electrode increases the specific surface area of the electrode and enhances the charge transfer capability so as to cause considerable improvement of the electrochemical activity for the anode reaction in a MFC. The performance of the MFC using CNTs/graphite felt electrode has been compared against a plain graphite felt electrode based MFC. A CNTs/graphite felt electrode showed as high as 15% increase in the power density (252 mW/m2) compared to graphite felt electrode (214 mW/m2). The CNTs/graphite felt anode therefore offers good prospects for application in MFCs.

摘要

微生物燃料电池(MFC)是一种利用微生物的催化反应将化学能转化为电能的装置。我们研究了采用碳纳米管(CNTs)/石墨毡复合电极的无介体MFC的性能。向石墨毡电极中添加碳纳米管可增加电极的比表面积并增强电荷转移能力,从而使MFC中阳极反应的电化学活性得到显著改善。已将使用碳纳米管/石墨毡电极的MFC的性能与基于普通石墨毡电极的MFC进行了比较。与石墨毡电极(214 mW/m2)相比,碳纳米管/石墨毡电极的功率密度提高了15%,高达252 mW/m2。因此,碳纳米管/石墨毡阳极在MFC中的应用前景良好。

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