SF4·N(C2H5)3：首个被明确鉴定的 SF4 加合物与有机碱。
SF4·N(C2H5)3: the first conclusively characterized SF4 adduct with an organic base.
机构信息
Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta T1K 3M4, Canada.
出版信息
Chem Commun (Camb). 2012 Sep 21;48(73):9120-2. doi: 10.1039/c2cc34578a. Epub 2012 Aug 6.
PMID:22864008
Abstract
Sulfur tetrafluoride and triethylamine react at low temperatures to form a 1:1 adduct. The unambiguous characterization of the SF(4)·N(C(2)H(5))(3), which is only stable at low temperature, proves the Lewis acid property of SF(4) towards organic Lewis bases. The S-N bond has a length of 2.384(2) Å and is an archetypical example of a dative S(IV) ← N bonding modality.
摘要
四氟化硫和三乙胺在低温下反应，形成 1:1 的加合物。SF(4)·N(C(2)H(5))(3) 的明确特征仅在低温下稳定，证明了 SF(4) 对有机路易斯碱的路易斯酸性质。S-N 键长为 2.384(2) Å，是典型的 dative S(IV) ← N 键合模式。
Zotero 插件