School of Chemistry, The University of Sydney, F11, NSW 2006, Australia.
Chem Soc Rev. 2013 Feb 21;42(4):1713-27. doi: 10.1039/c2cs35218d. Epub 2012 Aug 15.
In this tutorial review the use of macrocyclic complexes as building blocks in a selection of supramolecular systems is discussed with emphasis on the properties, such as enhanced stabilities, that cyclic ligands and their complexes may impart on the resulting assemblies. An aim of the review is to exemplify the versatility of macrocyclic ligand complexes for use as components in a range of both discrete and polymeric systems. The use of macrocyclic systems for controlling CuI aggregation, as scaffolds for metal-cluster formation, as the cyclic components in interlocked catenane and rotaxane structures, for constructing assemblies based on macrocycle exo-coordination, for forming columnar stacks, as well as their roles as both structural and redox centres in a range of coordination polymer types are all presented.
在本教程中，我们将讨论大环配合物作为构建块在一系列超分子体系中的应用，重点介绍环状配体及其配合物可能赋予所得组装体的特性，如增强的稳定性。本综述的目的之一是举例说明大环配体配合物作为一系列离散和聚合体系中组件的多功能性。大环体系在控制 CuI 聚集、作为金属簇形成的支架、作为互锁轮烷和索烃结构中环的组成部分、用于构建基于大环外配位的组装体、形成柱状堆积以及在一系列配位聚合物类型中作为结构和氧化还原中心的作用都将被呈现。
